., Suharso Synthesis of a Novel Calix[4]resorcinarene-Chitosan Hybrid. ORIENTAL JOURNAL OF CHEMISTRY, 34 (1). pp. 30-37. ISSN 0970-020 X

[img]
Preview
Text
Suharso OJC_Vol 34_No1-2018.pdf

Download (150kB) | Preview
Official URL: http://www.orientjchem.org/

Abstract

Synthesis of a novel calix[4]resorcinarene-chitosan hybrid using vanillin as raw material has been conducted. The synthesis was carried out in four steps i.e. (1) allylation of vanillin, (2) HCl-catalyzed condensation allyl vanillin with resorcinol, (3) chloromethylation of C-4-allyloxy-3-methoxyphenylcalix[4] resorcinarene with paraformaldehyde and HCl in the presence of ZnCl2 to yield tetrakis-chloromethyl-C-4-allyloxy-3 methoxyphenylcalix[4] resorcinarene, and (4) reaction of tetrakis-chloromethyl-C-4-allyloxy-3-methoxyphenylcalix[4] resorcinarene with chitosan to yield calixarene-chitosan hybrid. Structure elucidation of products were performed using FT-IR, 1H-NMR, 13C-NMR, GC-MS, XRD, and SEM. The product of calixarene-chitosan hybrid was obtained as dark red solid with m.p. > 300 °C in 78% yield.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Fakultas Matematika dan Ilmu Pengetahuan Alam (FMIPA) > Prodi Kimia
Depositing User: SUHARSO
Date Deposited: 31 Oct 2018 02:47
Last Modified: 31 Oct 2018 02:47
URI: http://repository.lppm.unila.ac.id/id/eprint/9100

Actions (login required)

View Item View Item