Haryanto, Agus and Fernando, Sandun D. and Adhikari, Sushil (2007) Ultrahigh temperature water gas shift catalysts to increase hydrogen yield from biomass gasification. Catalysis Today, 129. pp. 269-274.
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Abstract
Noble metal (Rh, Pt, Pd, Ir, Ru, and Ag) and Ni catalysts supported on CeO2–Al2O3 were investigated for water gas shift reaction at ultrahigh temperatures. Pt/CeO2–Al2O3 and Ru/CeO2–Al2O3 demonstrated as the best catalysts in terms of activity, hydrogen yield and hydrogen selectivity. At 700 8C and steam to CO ratio of 5.2:1, Pt/CeO2–Al2O3 converted 76.3% of CO with 94.7% of hydrogen selectivity. At the same conditions, the activity and hydrogen selectivity for Ru/CeO2–Al2O3 were 63.9% and 85.6%, respectively. Both catalysts showed a good stability over 9 h of continuous operation. However, both catalysts showed slight deactivation during the test period. The study revealed that Pt/CeO2–Al2O3 and Ru/CeO2–Al2O3 were excellent ultrahigh temperature water gas shift catalysts, which can be coupled with biomass gasification in a downstream reactor.
| Item Type: | Article |
|---|---|
| Subjects: | T Technology > TP Chemical technology |
| Divisions: | Fakultas Pertanian (FP) > Prodi Teknik Pertanian |
| Depositing User: | Dr. Ir. AGUS HARYANTO |
| Date Deposited: | 13 Oct 2016 15:35 |
| Last Modified: | 04 Nov 2016 03:23 |
| URI: | http://repository.lppm.unila.ac.id/id/eprint/741 |
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