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., Buhani and ., Narsito and ., Nuryono and Sri Kunarti, Eko and ., Suharso (2015) Adsorption competition of Cu(II) ion in ionic pair and multi-metal solution by ionic imprinted amino-silica hybrid adsorbent. Desalination and Water Treatment, 55 (5). pp. 1240-1252. ISSN 19443994, 19443986

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Abstract

It was carried out the synthesis of the Cu(II) ionic imprinted polymer (Cu(II)-IIP) material of amino-silica hybrid via sol-gel process using a tetraethyl-orthosilicate precursor and an active compound 3-aminopropyltrimetoxyslane. Adsorption process of Cu(II) ion on nonimprinted ionic (NIP) material and Cu(II)-IIP follows pseudo-first-order kinetics model with the value of adsorption rate constants (k1) 0.030 and 0.058L/min and Langmuir adsorption isotherm with the value of adsorption capacity 29.556 and 71.400mg/g, respectively. Adsorption competition data in ion pair solution of Cu(II)/Ag(I), Cu(II)/Zn(II), Cu(II)/Ni (II), and Cu(II)/Cd(II) showed that the Cu(II)-IIP adsorbent was more selective than NIP with value of selectivity coefficient (α)>1. A tendency of metal ion adsorbed in multi-metal solution follows this order: Ca(II) <Cd(II) <Ni(II)<Zn(II)<Ag(I)<Cu(II). The Cu(II)-IIP is stable chemically and it can be reused for adsorption of Cu(II) ion in solution without reduction of its capacity.

Item Type: Article
Uncontrolled Keywords: Cu(II) ionic imprinted; Selective adsorption; Sol-gel; Amino-silica hybrid
Subjects: Q Science > QD Chemistry
Divisions: Fakultas Matematika dan Ilmu Pengetahuan Alam (FMIPA) > Prodi Kimia
Depositing User: SUHARSO
Date Deposited: 07 Dec 2017 04:06
Last Modified: 07 Dec 2017 04:06
URI: http://repository.lppm.unila.ac.id/id/eprint/6123

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