Hadi, Sutopo (2020) The Reactions of Tetramer Platinum(IV) Complexes, [{Pt(CH3)2X2}4], (X = Cl, Br, and I) with Pyridine. Revista de Chimie, 71 (4). pp. 230-234. ISSN 2668-8212
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Official URL: https://revistadechimie.ro/RCAbout.asp
Abstract
The reactions of tetramer platinum(IV) complexes, [{Pt(CH3)2X2}4] (X = Cl, Br, and I), the final product obtained from the reaction between fac-[Pt(CH3)2(OCH3)(H2O)3]+ and halide salts, were investigated. These tetramers were insoluble in many non-coordinating solvents such as acetone, diethylether and chloroform, however they did dissolve in dry pyridine to give [Pt(CH3)2X2(py)2] complexes. The product obtained was confirmed with NMR spectroscopy [1H, 13C and 195Pt).
Item Type: | Article |
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Uncontrolled Keywords: | cubane structure, NMR, pyridine, tetramer platinum(IV) complexes |
Subjects: | Q Science > QD Chemistry |
Divisions: | Fakultas Matematika dan Ilmu Pengetahuan Alam (FMIPA) > Prodi Magister Ilmu Kimia |
Depositing User: | Prof. Sutopo Hadi |
Date Deposited: | 05 May 2020 04:53 |
Last Modified: | 05 May 2020 04:53 |
URI: | http://repository.lppm.unila.ac.id/id/eprint/19440 |
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