Kiswandono, Agung Abadi and Sutopo, Hadi (2019) Synthesis and characterization of co-edaf and its application test as a carrier membrane for phenol transport using polymer inclusion membrane (PIM). Synthesis and characterization of co-edaf and its application test as a carrier membrane for phenol transport using polymer inclusion membrane (PIM), 23 (5). pp. 1-9. ISSN E-ISSN No. 2278 - 4535; PRINT-ISSN 0973-6263

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Abstract

The development of a new compound derived from polyeugenol as carrier compound in phenol transport has been successfully performed. The compound of copoly(eugenol-dialyl phthalate) or co-EDAF was synthesized by reacting eugenol and dialyl phthalate agent through a polymerization process using boron tri-fluorodiethyl ether as a catalyst. The obtained compound was then tested for its ability as a carrier compound in phenol transport using polymer inclusion membrane (PIM) method. The synthesized compound was characterized by using FTIR, SEM and TG-DTA analytical methods. Based on the results of characterization, it was shown that co-EDAF has been successfully obtained. The loss of the absorbance band at the wavenumber of 995.27 cm-1 suggests that the unsaturated vinyl group (-CH = CH2) in eugenol has undergone successful polymerization process. The TG-DTA data also support the success of the polymerization process as indicated by the differences in temperature T5%, T20%, T50% and Tmax in co-EDAF from those of the control compound polyeugenol. Furthermore, the carrier test in phenol transport has also demonstrated that the membrane containing the co-EDAF can effectively serve as a carrier compound as shown by its ability to transport phenol repeatedly.

Item Type:	Article
Subjects:	Q Science > QD Chemistry
Divisions:	Fakultas Matematika dan Ilmu Pengetahuan Alam (FMIPA) > Prodi Kimia
Depositing User:	Dr Agung Abadi Kiswandono
Date Deposited:	10 May 2019 02:34
Last Modified:	10 May 2019 02:34
URI:	http://repository.lppm.unila.ac.id/id/eprint/12403

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