Hadi, Sutopo and Irawan, Bambang and Noviany, Noviany and Yandri, Yandri and Suhartati, Tati (2021) REACTIONS OF A TRANS-DIAMMINEDIAQUAPLATINUM(II) COMPLEX WITH L-CYSTEINE. Macedonian Journal of Chemistry and Chemical Engineering, 40 (2). ISSN 1857-5552
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Abstract
The reaction of a trans-diamminediaquaplatinum(II) complex, trans-[Pt(15NH3)2(H2O)2] 2+ (1), and L-cysteine (R–SH) has been performed to confirm the formation of the products in the solution. The reaction was monitored by 1-D 15N and 2-D [1H, 15N] heteronuclear single-quantum coherence (HSQC) Nuclear Magnetic Resonance (NMR) and electrospray ionization (ESI) mass spectrometry. The reaction was initially performed in an alkaline solution; the platinum mononuclear species products were observed. The pH of the solution was then decreased to an acidic solution; the products obtained were oligomeric platinum products. Based on the spectrum from mass spectrometry, which was obtained in a basic solution, the most dominant complex in the solution is a dinuclear platinum(II) species with a sulfur-bridging, trans-[{Pt(S-cys)2( 15NH3)2}2(S-cys)]+ having m/z of 822. The loss of two successive ammines was observed.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > Q Science (General) |
| Divisions: | Fakultas Matematika dan Ilmu Pengetahuan Alam (FMIPA) > Prodi Biologi |
| Depositing User: | BAMBANG IR |
| Date Deposited: | 24 Jan 2022 09:06 |
| Last Modified: | 24 Jan 2022 09:06 |
| URI: | http://repository.lppm.unila.ac.id/id/eprint/38265 |
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