., Buhani and Herasari, Dian and Suharso, S and Dwi Yuwono, Suripto (2017) Correlation of Ionic Imprinting Cavity Sites on the Amino-Silica Hybrid Adsorbent with Adsorption Rate and Capacity of Cd2+ Ion in Solution. Oriental Journal of Chemistry, 33 (1). pp. 418-429. ISSN 0970-020 X

OJC Vol33 No1 p418-429-2017.pdf

Download (1MB) | Preview
Official URL: http://www.orientjchem.org


In this research, it has been evaluated concentration effect of Cd2+ ion used as the Cd2+ ionic imprinted on synthesis of the Cd2+ ionic imprinted amino-silica hybrid (Cd(II)-IIP) adsorbent to adsorption rate and capacity of the target ion (Cd2+) in solution. The results of the ionic imprinting (as active sites of Cd2+ ion) obtained were prepared from different concentrations of the Cd2+ ion producing the different ionic imprinted cavity fraction. The concentrations of Cd2+ ion used as the ionic imprinting were 0.05, 0.10, and 0.15 mol L-1 resulting the ionic imprinted cavity fraction for each 97.89 (Cd(II)-IIPa), 98.49 (Cd(II)-IIPb), and 95.82 % (Cd(II)-IIPc), respectively. From the adsorption data obtained, they show that initial concentration differences of the imprinted Cd2+ ion produce different adsorption models of the Cd2+ ion. The bigger the Cd2+ ionic imprinting fraction, the higher the adsorption rate (k1) and capacity (q) of Cd2+ ion on the adsorbent.

Item Type: Article
Uncontrolled Keywords: Imprinted ionic; Adsorption; Amino-silica hybrid; Adsorption active site
Subjects: Q Science > QD Chemistry
Divisions: Fakultas Matematika dan Ilmu Pengetahuan Alam (FMIPA) > Prodi Kimia
Depositing User: SUHARSO
Date Deposited: 07 Jun 2017 09:22
Last Modified: 15 Dec 2017 01:24
URI: http://repository.lppm.unila.ac.id/id/eprint/2959

Actions (login required)

View Item View Item