Rangganita, Fully reha and Hermida, Lilis and Angraeni, Archealin and Khoirunnisa, Destiara
(2016)
Synthesis and Reusability Study of Sulfated Zirconia
Functionalized SBA-15 for Esterification of Oleic
Acid to Produce TMPTO as Biolubricant.
In: 9th Conference of Indonesian Student Association in Korea (CISAK), 3 - 4 September 2016, Korea.
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Abstract
The synthesis of SZr-SBA-15 catalsyt was prepared by using urea hydrolisis method. SBA-15 incoporated with sulfated
zirconia was prepared by reacting SBA-15 with Zirkoniumoxychloride and urea at 90oC to form ZrO2-SBA-15. Then H2SO4 was added to
ZrO2-SBA-15 at room temperature to form SZr-SBA-15. This SZr-SBA-15 catalyst was used to synthesize biolubricant oil via
esterification of oleic acid with TMP. The catalyst were characterized in terms of adsorption-desorption nitrogen analysis, SEM-EDX,
FTIR and biolubricant oil was characterized by FTIR analysis. Based on SEM-EDX and adsorption-desorption nitrogen analysis result, it
was found that Zr had been incorporate in SBA-15. The SZr-SBA-15 catalyst was an efficient solid catalyst for esterification of oleic acid
with TMP with high conversion (85,9%) and selektivity (63,7%) to Trimethylolpropanetrioleat. From the study of reusability, it was
found that SZr-SBA-15 catalyst could be used up to 3 rounds reaction without significant decrease in activity.
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Synthesis and Reusability Study of Sulfated Zirconia
Functionalized SBA-15 for Esterification of Oleic
Acid to Produce TMPTO as Biolubricant. (deposited 20 Jul 2017 08:52)
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