Hadi, Sutopo (2005) THE SYNTHESIS AND NMR STUDY ON THE STABILITY OF DIMETHYLMETHOXOPLATINUM(IV) COMPLEXES. Indonesian Journal of Chemistry, 5 (2). pp. 87-91. ISSN 1411 9420

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Abstract

The synthesis of two stable platinum(IV) complexes containing methoxo ligand, [Pt(CH3)2(OCH3)(OH)py2] (1) and fac-[Pt(CH3)2(OCH3)(H2O)3] (2), has been successfully performed. Complex 1 was prepared by oxidative addition reaction of cis-[Pt(CH3)2py2] with dry methanol, and a subsequent reaction of 1 with 70 % HClO4 in water produced the platinum complex 2. The stability of complex 2 in acidic aqueous solution was investigated and monitored with 1H and 195Pt NMR. The platinum complex 2 was found to be quite stable toward hydrolysis and no -hydride elimination was observed.

Item Type:	Article
Subjects:	Q Science > QA Mathematics Q Science > QD Chemistry
Divisions:	Fakultas Matematika dan Ilmu Pengetahuan Alam (FMIPA) > Prodi Kimia
Depositing User:	Prof. Sutopo Hadi
Date Deposited:	15 Nov 2016 04:16
Last Modified:	15 Nov 2016 04:16
URI:	http://repository.lppm.unila.ac.id/id/eprint/1166

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